Nature has been successful in self-assembling simple building blocks to complex functional architectures and the concept of supramolecular chemistry has enabled chemists to mimic nature's self-assembly principles. The understanding of the assembly/reassembly ...

The conformational preference of the cyano group of the 1-cyano-1-silacyclohexane was studied experimentally by means of gas electron diffraction (GED) and dynamic nuclear magnetic resonance (DNMR) as well as by quantum chemical (QC) calculations ...

Despite decades of research, the structure–activity relationship of nitrogenase is still not understood. Only recently was the full molecular structure of the FeMo cofactor (FeMoco) revealed, but the charge and metal oxidation states of FeMoco have ...